Earlier I posted many vinyl options here, considering them an improvement over leather. However, vinyl (polyvinylchloride) requires toxic chemicals during manufacture, and then slowly "de-gasses" these over its lifetime. A more sustainable non-leather option is polyurethane. There are some fabric makers involved with fake leather that is sustainable, but they don't make furniture.
Some sustainable options are available from:
http://www.viesso.com/products/model.php?cPath=3
http://www.qcollection.com/index.php?mode=tfo_showroom
http://www.greensage.com/furniturestore/pbHfurnasofas.html
Hammock:
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